High thermal conductivity and high electrical resistivity of poly(vinylidene fluoride)/polystyrene blends by controlling the localization of hybrid fillers
Identifieur interne : 000718 ( Main/Exploration ); précédent : 000717; suivant : 000719High thermal conductivity and high electrical resistivity of poly(vinylidene fluoride)/polystyrene blends by controlling the localization of hybrid fillers
Auteurs : Jian-Ping Cao [République populaire de Chine] ; JUN ZHAO [République populaire de Chine] ; XIAODONG ZHAO [République populaire de Chine] ; FENG YOU [République populaire de Chine] ; HAIZHU YU [République populaire de Chine] ; Guo-Hua Hu [France] ; Zhi-Min Dang [République populaire de Chine]Source :
- Composites science and technology [ 0266-3538 ] ; 2013.
Descripteurs français
- Pascal (Inist)
- Conductivité thermique, Résistivité électrique, Vinylidène fluorure polymère, Styrène polymère, Mélange polymère, Nanotube multifeuillets, Nanotube carbone, Carbure de silicium, Nanocomposite, Morphologie, Percolation, Composite hybride, Fraction volumique, Etude expérimentale, Propriété électrique, Propriété thermique, Céramique sans oxyde, Matériau composite.
- Wicri :
- topic : Matériau composite.
English descriptors
- KwdEn :
- Carbon nanotubes, Composite material, Electric resistivity, Electrical properties, Experimental study, Hybrid composite, Morphology, Multiwalled nanotube, Nanocomposite, Non oxide ceramics, Percolation, Polymer blends, Silicon carbide, Styrene polymer, Thermal conductivity, Thermal properties, Vinylidene fluoride polymer, Volume fraction.
Abstract
Both high thermal conductivity and high electrical resistivity of immiscible poly(vinylidene fluoride) (PVDF)/polystyrene (PS) 30/70 blends are achieved by controlling the localization of hybrid fillers of multi-walled carbon nanotubes (MWCNTs) and silicon carbide (SiC) nanoparticles. The selective localization of both fillers in the minor phase of PVDF by using the masterbatch technique is confirmed by the scanning electron microscopy (SEM) observation. The domain size of the PVDF phase can be significantly reduced by further adding the fillers. The percolation threshold of MWCNTs in PVDF/PS 30/70 blend is measured to be ca. 2.9 vol% with respect to the whole system. Compared with the case where only MWCNTs or SiC nanoparticles are present in the PVDF phase, the selective localization of both fillers in the PVDF phase can yield higher thermal conductivity and higher alternating current (AC) resistivity. Such materials could have potential applications in the electronic industry.
Url:
Affiliations:
- France, République populaire de Chine
- Grand Est, Lorraine (région)
- Nancy, Pékin
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine
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Le document en format XML
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ZHAO</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing</s1><s2>Beijing 100083</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>République populaire de Chine</country><placeName><settlement type="city">Pékin</settlement></placeName></affiliation></author><author><name sortKey="Xiaodong Zhao" sort="Xiaodong Zhao" uniqKey="Xiaodong Zhao" last="Xiaodong Zhao">XIAODONG ZHAO</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing</s1><s2>Beijing 100083</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>République populaire de Chine</country><placeName><settlement type="city">Pékin</settlement></placeName></affiliation></author><author><name sortKey="Feng You" sort="Feng You" uniqKey="Feng You" last="Feng You">FENG YOU</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing</s1><s2>Beijing 100083</s2><s3>CHN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>République populaire de Chine</country><placeName><settlement type="city">Pékin</settlement></placeName></affiliation></author><author><name sortKey="Haizhu Yu" sort="Haizhu Yu" uniqKey="Haizhu Yu" last="Haizhu Yu">HAIZHU YU</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing</s1><s2>Beijing 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when="2013">2013</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Composites science and technology</title><title level="j" type="abbreviated">Compos. sci. technol.</title><idno type="ISSN">0266-3538</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carbon nanotubes</term><term>Composite material</term><term>Electric resistivity</term><term>Electrical properties</term><term>Experimental study</term><term>Hybrid composite</term><term>Morphology</term><term>Multiwalled nanotube</term><term>Nanocomposite</term><term>Non oxide ceramics</term><term>Percolation</term><term>Polymer blends</term><term>Silicon carbide</term><term>Styrene polymer</term><term>Thermal conductivity</term><term>Thermal properties</term><term>Vinylidene fluoride polymer</term><term>Volume fraction</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Conductivité thermique</term><term>Résistivité électrique</term><term>Vinylidène fluorure polymère</term><term>Styrène polymère</term><term>Mélange polymère</term><term>Nanotube multifeuillets</term><term>Nanotube carbone</term><term>Carbure de silicium</term><term>Nanocomposite</term><term>Morphologie</term><term>Percolation</term><term>Composite hybride</term><term>Fraction volumique</term><term>Etude expérimentale</term><term>Propriété électrique</term><term>Propriété thermique</term><term>Céramique sans oxyde</term><term>Matériau composite</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Matériau composite</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Both high thermal conductivity and high electrical resistivity of immiscible poly(vinylidene fluoride) (PVDF)/polystyrene (PS) 30/70 blends are achieved by controlling the localization of hybrid fillers of multi-walled carbon nanotubes (MWCNTs) and silicon carbide (SiC) nanoparticles. The selective localization of both fillers in the minor phase of PVDF by using the masterbatch technique is confirmed by the scanning electron microscopy (SEM) observation. The domain size of the PVDF phase can be significantly reduced by further adding the fillers. The percolation threshold of MWCNTs in PVDF/PS 30/70 blend is measured to be ca. 2.9 vol% with respect to the whole system. Compared with the case where only MWCNTs or SiC nanoparticles are present in the PVDF phase, the selective localization of both fillers in the PVDF phase can yield higher thermal conductivity and higher alternating current (AC) resistivity. Such materials could have potential applications in the electronic industry.</div></front></TEI><affiliations><list><country><li>France</li><li>République populaire de Chine</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li><li>Pékin</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Université de Lorraine</li></orgName></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Cao, Jian Ping" sort="Cao, Jian Ping" uniqKey="Cao J" first="Jian-Ping" last="Cao">Jian-Ping Cao</name></noRegion><name sortKey="Dang, Zhi Min" sort="Dang, Zhi Min" uniqKey="Dang Z" first="Zhi-Min" last="Dang">Zhi-Min Dang</name><name sortKey="Feng You" sort="Feng You" uniqKey="Feng You" last="Feng You">FENG YOU</name><name sortKey="Haizhu Yu" sort="Haizhu Yu" uniqKey="Haizhu Yu" last="Haizhu Yu">HAIZHU YU</name><name sortKey="Jun Zhao" sort="Jun Zhao" uniqKey="Jun Zhao" last="Jun Zhao">JUN ZHAO</name><name sortKey="Xiaodong Zhao" sort="Xiaodong Zhao" uniqKey="Xiaodong Zhao" last="Xiaodong Zhao">XIAODONG ZHAO</name></country><country name="France"><region name="Grand Est"><name sortKey="Hu, Guo Hua" sort="Hu, Guo Hua" uniqKey="Hu G" first="Guo-Hua" last="Hu">Guo-Hua Hu</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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